The Devil
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The name the Devil refers to the Angel named Lucifer. It has been mentioned numerous times throughout Season five. Lucifer tells Nick that people refer to him as "Satan" and the "Devil”. This was also corroborated in 5.04 The End. According to Lucifer the name "The Devil" was a man given title; humans gave him this title/name for his bad reputation. Lucifer tells Nick that the title doesn't fit and that he was cast down for loving God too much.
For More Info on this character see the page titled Lucifer.