Clairsentience
From Super-wiki
Clairsentience is the ability to sense energies and things that are not visible to the naked eye.
Episodes
1.09 Home
When Missouri Moseley went into the Winchester's original house, she was able to detect supernatural energies, saying one was a poltergeist.
4.20 The Rapture
When Sam started drinking demon blood again, Anna Milton was able to detect it, saying he looked "different."
13.02 The Rising Son
When Apocalypse World Michael met Lucifer, he mentions he knew he was truly Lucifer, stating that he could "feel it."